Tetracationic Gallium Cluster Cations | Zendy

Glootz Kim | Zendy; Kratzert Daniel | Zendy; Himmel Daniel | Zendy; Kastro Aho | Zendy; Yassine Zeinab | Zendy; Findeisen Tobias | Zendy; Krossing Ingo | Zendy

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Tetracationic Gallium Cluster Cations

Author(s) -

Glootz Kim,

Kratzert Daniel,

Himmel Daniel,

Kastro Aho,

Yassine Zeinab,

Findeisen Tobias,

Krossing Ingo

Publication year - 2018

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201807486

Subject(s) - gallium , chemistry , cluster (spacecraft) , crystallography , metal , salt (chemistry) , energetics , phenanthroline , stereochemistry , inorganic chemistry , physics , organic chemistry , thermodynamics , computer science , programming language

The univalent salt Ga(PhF) 2 + [Al(OR F ) 4 ] − (R F =OC(CF 3 ) 3 ) forms the strongly metal–metal bonded cluster tetracations [Ga II 2 (L) 4 ] 4+ and [Ga I 4 (L′) 8 ] 4+ , when it reacts with innocent ligands like phenanthroline (L=phen) or t ‐butylisonitrile (L′= t Bu‐NC). Their structures and energetics are discussed as a function of the employed ligands, supported by DFT calculations and Born–Fajans–Haber cycles.

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