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Premium Alkali Metal Species in the Reversible Activation of H 2
Author(s)
Xu Maotong,
Jupp Andrew R.,
Qu ZhengWang,
Stephan Douglas W.
Publication year2018
Publication title
angewandte chemie
Resource typeJournals
PublisherWiley
Abstract MP( t Bu) 2 (M=Li, Na, K), KH and KN(SiMe 3 ) 2 are shown to activate HD reversibly. In the case of MP( t Bu) 2 this leads to isotopic scrambling and the formation of H 2 , D 2 , H(D)P( t Bu) 2 and MH(D) in C 6 D 6 . In toluene, KP( t Bu) 2 reacts with H 2 but also leads to isotopic scrambling into the methyl groups of the solvent toluene. DFT calculations reveal that these systems effect H 2 activation via cooperative interactions with the Lewis acidic alkali metal and the basic phosphorus, carbanion, or hydride centres, mimicking frustrated Lewis pair (FLP) behaviour.
Subject(s)alkali metal , chemistry , inorganic chemistry , metal , organic chemistry
Language(s)English
eISSN1521-3757
pISSN0044-8249
DOI10.1002/ange.201806849

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