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Tunable Chiroptical Properties from the Plasmonic Band to Metal–Ligand Charge Transfer Band of Cysteine‐Capped Molybdenum Oxide Nanoparticles
Author(s) -
Li Yiwen,
Cheng Jiaji,
Li Jiagen,
Zhu Xi,
He Tingchao,
Chen Rui,
Tang Zikang
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201806093
Subject(s) - chirality (physics) , nanoparticle , plasmon , materials science , circular dichroism , molecule , oxide , molybdenum , ligand (biochemistry) , nanotechnology , photochemistry , chemistry , crystallography , optoelectronics , organic chemistry , biochemistry , physics , chiral symmetry breaking , receptor , quantum mechanics , nambu–jona lasinio model , metallurgy , quark
Understanding the interactions between a semiconducting nanocrystal surface and chiral anchoring molecules could resolve the mechanism of chirality induction in nanoscale and facilitate the rational design of chiral semiconducting materials for chiroptics. Now, chiral molybdenum oxide nanoparticles are presented in which chirality is transferred via a bio‐to‐nano approach. With facile control of the amount of chiral cysteine molecules under redox treatment, circular dichroism (CD) signals are generated in the plasmon region and metal–ligand charge‐transfer band. The obtained enhanced CD signals with tunable lineshapes illustrate the possibility of using chiral molybdenum oxide nanoparticles as potentials for chiral semiconductor nanosensors, optoelectronics, and photocatalysts.