Construction of Quaternary Stereocenters by Palladium‐Catalyzed Carbopalladation‐Initiated Cascade Reactions | Zendy

Ping Yuanyuan | Zendy; Li Yuxiu | Zendy; Zhu Jieping | Zendy; Kong Wangqing | Zendy

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Construction of Quaternary Stereocenters by Palladium‐Catalyzed Carbopalladation‐Initiated Cascade Reactions

Author(s) -

Ping Yuanyuan,

Li Yuxiu,

Zhu Jieping,

Kong Wangqing

Publication year - 2019

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201806088

Subject(s) - stereocenter , domino , enantioselective synthesis , palladium , chemistry , cascade reaction , cascade , combinatorial chemistry , catalysis , stereochemistry , organic chemistry , chromatography

The enantioselective synthesis of molecules containing quaternary stereocenters is a field of intense research interest and development. Among the known organic transformations, carbopalladation‐initiated domino transformations constitutes a general method for the construction of compounds containing cyclic or spiro quaternary stereocenters. In this Minireview, recent achievements in palladium‐catalyzed domino Heck/C−H functionalizations and developments in enantioselective carbopalladation‐initiated domino processes are summarized.

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