Reaction of CO 2  with a Vanadium(II) Aryl Oxide: Synergistic Activation of CO 2 /Oxo Groups towards H‐Atom Radical Abstraction | Zendy

Viasus Camilo J. | Zendy; Alderman Nicholas P. | Zendy; Gabidullin Bulat | Zendy; Gambarotta Sandro | Zendy

Premium

Reaction of CO 2 with a Vanadium(II) Aryl Oxide: Synergistic Activation of CO 2 /Oxo Groups towards H‐Atom Radical Abstraction

Author(s) -

Viasus Camilo J.,

Alderman Nicholas P.,

Gabidullin Bulat,

Gambarotta Sandro

Publication year - 2018

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201805569

Subject(s) - chemistry , formate , deoxygenation , aryl , medicinal chemistry , vanadium , hydrogen atom abstraction , atom (system on chip) , stereochemistry , radical , inorganic chemistry , catalysis , organic chemistry , alkyl , computer science , embedded system

Treatment of divalent (ONNO)V(TMEDA) ( 1 ; ONNO=[2,4‐Me 2 ‐2‐(OH)C 6 H 2 CH 2 ] 2 N(CH 2 ) 2 NMe 2 ) with CO 2 afforded [(ONNO)V] 2 (μ‐OH)(μ‐formate) ( 2 ). Whereas the bridging hydroxo and formate groups both originated from CO 2 , the H atoms present on the two residues were obtained through H‐atom radical abstraction from the solvent. DFT calculations revealed an initially linear CO 2 bonding mode, followed by deoxygenation, and highlighted a synergistic effect between the so‐formed oxo group and an additional bridging CO 2 residue in promoting radical behavior.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research