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A General Synthesis of Phosphorus‐ and Arsenic‐Containing Analogues of the Thio‐ and Seleno‐cyanate Anions
Author(s) -
Tambornino Frank,
Hinz Alexander,
Köppe Ralf,
Goicoechea Jose M.
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201805348
Subject(s) - arsenic , thio , chemistry , cyanate , phosphorus , combinatorial chemistry , inorganic chemistry , organic chemistry
A general synthetic protocol for the synthesis of phosphorus‐ and arsenic‐containing analogues of the thio‐ and seleno‐cyanate anions is reported. This procedure allows for the isolation of three unprecedented species: the phosphaethynselenolate, PCSe − ( 1 ), the arsaethynthiolate, AsCS − ( 2 ), and the arsaethynselenolate, AsCSe − ( 3 ), anions. The structures, electronic properties, and spectroscopic signatures of these species are reported.