MOF‐Derived Hollow CoS Decorated with CeO  x   Nanoparticles for Boosting Oxygen Evolution Reaction Electrocatalysis | Zendy

Xu Huajie | Zendy; Cao Jing | Zendy; Shan Changfu | Zendy; Wang Bingkai | Zendy; Xi Pinxian | Zendy; Liu Weisheng | Zendy; Tang Yu | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

MOF‐Derived Hollow CoS Decorated with CeO x Nanoparticles for Boosting Oxygen Evolution Reaction Electrocatalysis

Author(s) -

Xu Huajie,

Cao Jing,

Shan Changfu,

Wang Bingkai,

Xi Pinxian,

Liu Weisheng,

Tang Yu

Publication year - 2018

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201804673

Subject(s) - electrocatalyst , oxygen evolution , materials science , nanoparticle , nanocages , cobalt , nanostructure , chemical engineering , catalysis , transition metal , oxygen , nanotechnology , chemistry , electrode , electrochemistry , metallurgy , organic chemistry , engineering

Transition‐metal sulfides (TMSs) have emerged as important candidates for oxygen evolution reaction (OER) electrocatalysts. Now a hybrid nanostructure has been decorated with CeO x nanoparticles on the surface of ZIF‐67‐derived hollow CoS through in situ generation. Proper control of the amount of CeO x on the surface of CoS can achieve precise tuning of Co 2+ /Co 3+ ratio, especially for the induced defects, further boosting the OER activity. Meanwhile, the formation of protective CeO x thin layer effectively inhibits the corrosion by losing cobalt ion species from the active surface into the solution. It is thus a rare example of a hybrid hetero‐structural electrocatalyst with CeO x NPs to improve the performance of the hollow TMS nanocage.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research