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Three‐Dimensional Heterocycles by Iron‐Catalyzed Ring‐Closing Sulfoxide Imidation
Author(s) -
Yu Hao,
Li Zhen,
Bolm Carsten
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201804284
Subject(s) - sulfoxide , intramolecular force , ring (chemistry) , chemistry , catalysis , combinatorial chemistry , atom (system on chip) , functional group , polymer chemistry , organic chemistry , computer science , polymer , embedded system
A general and atom‐economical method for the synthesis of cyclic sulfoximines by intramolecular imidations of azido‐containing sulfoxides using a commercially available Fe II phthalocyanine (Fe II Pc) as catalyst has been developed. The method conveys a broad functional group tolerance and the resulting three‐dimensional heterocycles can be modified by cross‐coupling reactions.
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