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Redox Chemistry of Molybdenum Trioxide for Ultrafast Hydrogen‐Ion Storage
Author(s) -
Wang Xianfu,
Xie Yiming,
Tang Kai,
Wang Chao,
Yan Chenglin
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201803664
Subject(s) - molybdenum trioxide , chemistry , inorganic chemistry , faraday efficiency , hydrogen storage , redox , hydrogen , electrolyte , reversible hydrogen electrode , molybdenum , standard hydrogen electrode , ion , electrode , reference electrode , organic chemistry
Hydrogen ions are ideal charge carriers for rechargeable batteries due to their small ionic radius and wide availability. However, little attention has been paid to hydrogen‐ion storage devices because they generally deliver relatively low Coulombic efficiency as a result of the hydrogen evolution reaction that occurs in an aqueous electrolyte. Herein, we successfully demonstrate that hydrogen ions can be electrochemically stored in an inorganic molybdenum trioxide (MoO 3 ) electrode with high Coulombic efficiency and stability. The as‐obtained electrode exhibits ultrafast hydrogen‐ion storage properties with a specific capacity of 88 mA hg −1 at an ultrahigh rate of 100 C. The redox reaction mechanism of the MoO 3 electrode in the hydrogen‐ion cell was investigated in detail. The results reveal a conversion reaction of the MoO 3 electrode into H 0.88 MoO 3 during the first hydrogen‐ion insertion process and reversible intercalation/deintercalation of hydrogen ions between H 0.88 MoO 3 and H 0.12 MoO 3 during the following cycles. This study reveals new opportunities for the development of high‐power energy storage devices with lightweight elements.