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Hypervalent Iodine(III)‐Catalyzed Balz–Schiemann Fluorination under Mild Conditions
Author(s) -
Xing Bo,
Ni Chuanfa,
Hu Jinbo
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201802466
Subject(s) - hypervalent molecule , iodine , catalysis , chemistry , reaction conditions , organic chemistry , combinatorial chemistry
An unprecedented hypervalent iodine(III) catalyzed Balz–Schiemann reaction is described. In the presence of a hypervalent iodine compound, the fluorination reaction proceeds under mild conditions (25–60 °C), and features a wide substrate scope and good functional‐group compatibility.