Brønsted Acid Enabled Nickel‐Catalyzed Hydroalkenylation of Aldehydes with Styrene and its Derivatives | Zendy

Han XingWang | Zendy; Zhang Tao | Zendy; Zheng YanLong | Zendy; Yao WeiWei | Zendy; Li JiangFei | Zendy; Pu YouGe | Zendy; Ye Mengchun | Zendy; Zhou QiLin | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Brønsted Acid Enabled Nickel‐Catalyzed Hydroalkenylation of Aldehydes with Styrene and its Derivatives

Author(s) -

Han XingWang,

Zhang Tao,

Zheng YanLong,

Yao WeiWei,

Li JiangFei,

Pu YouGe,

Ye Mengchun,

Zhou QiLin

Publication year - 2018

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201801817

Subject(s) - styrene , brønsted–lowry acid–base theory , chemistry , aldehyde , catalysis , alkene , yield (engineering) , nickel , selectivity , allylic rearrangement , organic chemistry , copolymer , materials science , polymer , metallurgy

A Brønsted acid enabled nickel‐catalyzed hydroalkenylation of aldehydes and styrene derivatives has been developed. The Brønsted acid acts as a proton shuttle to transfer a proton from the alkene to the aldehyde, thereby leading to an economical and byproduct‐free coupling. A series of synthetically useful allylic alcohols were obtained through one‐step reactions from readily available styrene derivatives and aliphatic aldehydes in up to 88 % yield and with high linear selectivity.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research