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Rhodium‐Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three‐Membered Carbocycles
Author(s) -
Dian Longyang,
Marek Ilan
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201713324
Subject(s) - rhodium , chemistry , cyclopropene , catalysis , aryl , surface modification , combinatorial chemistry , organic chemistry , alkyl
A variety of highly diastereo‐ and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium‐catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of ( R , S )‐Josiphos.