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Thermoregulated Phase‐Transition Synthesis of Two‐Dimensional Carbon Nanoplates Rich in sp 2 Carbon and Unimodal Ultramicropores for Kinetic Gas Separation
Author(s) -
Zhang LuHua,
Li WenCui,
Liu Hong,
Wang QuanGao,
Tang Lei,
Hu QingTao,
Xu WenJing,
Qiao WeiHong,
Lu ZhongYuan,
Lu AnHui
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201712913
Subject(s) - crystallite , carbon fibers , sorption , adsorption , selectivity , chemical engineering , materials science , phase (matter) , stacking , chemistry , crystallography , catalysis , organic chemistry , composite material , composite number , engineering
The development of highly selective, chemically stable and moisture‐resistant adsorbents is a key milestone for gas separation. Porous carbons featured with random orientation and cross‐linking of turbostratic nanodomains usually have a wide distribution of micropores. Here we have developed a thermoregulated phase‐transition‐assisted synthesis of carbon nanoplates with more than 80 % sp 2 carbon, unimodal ultramicropore and a controllable thickness. The thin structure allows oriented growth of carbon crystallites, and stacking of crystallites in nearly parallel orientation are responsible for the single size of the micropores. When used for gas separation from CH 4 , carbon nanoplates exhibit high uptakes (5.2, 5.3 and 5.1 mmol g −1 ) and selectivities (7, 71 and 386) for CO 2 , C 2 H 6 and C 3 H 8 under ambient conditions. The dynamic adsorption capacities are close to equilibrium uptakes of single components, further demonstrating superiority of carbon nanoplates in terms of selectivity and sorption kinetics.