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A Permselective CeO x Coating To Improve the Stability of Oxygen Evolution Electrocatalysts
Author(s) -
Obata Keisuke,
Takanabe Kazuhiro
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201712121
Subject(s) - oxygen evolution , catalysis , chemical engineering , redox , coating , anode , chemistry , oxygen , layer (electronics) , inorganic chemistry , materials science , electrode , nanotechnology , electrochemistry , organic chemistry , engineering
Abstract Highly active NiFeO x electrocatalysts for the oxygen evolution reaction (OER) suffer gradual deactivation with time owing to the loss of Fe species from the active sites into solution during catalysis. The anodic deposition of a CeO x layer prevents the loss of such Fe species from the OER catalysts, achieving a highly stable performance. The CeO x layer does not affect the OER activity of the catalyst underneath but exhibits unique permselectivity, allowing the permeation of OH − and O 2 through while preventing the diffusion of redox ions through the layer to function as a selective O 2 ‐evolving electrode. The use of such a permselective protective layer provides a new strategy for improving the durability of electrocatalysts.