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Ultrathin Graphdiyne Nanosheets Grown In Situ on Copper Nanowires and Their Performance as Lithium‐Ion Battery Anodes
Author(s) -
Shang Hong,
Zuo Zicheng,
Li Liang,
Wang Fan,
Liu Huibiao,
Li Yongjun,
Li Yuliang
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201711366
Subject(s) - anode , materials science , nanowire , lithium (medication) , nanostructure , ion , copper , nanotechnology , catalysis , battery (electricity) , in situ , chemical engineering , lithium ion battery , electrode , chemistry , metallurgy , organic chemistry , medicine , power (physics) , physics , quantum mechanics , endocrinology , engineering
A method is presented for the scalable preparation of high‐quality graphdiyne nanotubes and ultrathin graphdiyne nanosheets (average thickness: ca. 1.9 nm) using Cu nanowires as a catalyst. For the storage of Li + ions, the graphdiyne nanostructures show a high capacity of 1388 mAh g −1 and high rate performance (870 mA h g −1 at 10 A g −1 , and 449.8 mA h g −1 at 20 A g −1 ) with robust stability, demonstrating outstanding overall potential for its applications.