Premium
Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O 2 CCF 2 SO 2 F) and N ‐Fluorobenzenesulfonimide
Author(s) -
Liu Yongan,
Wu Hao,
Guo Yong,
Xiao JiChang,
Chen QingYun,
Liu Chao
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201709663
Subject(s) - trifluoromethyl , chemistry , sulfonyl , intermolecular force , atom (system on chip) , combinatorial chemistry , medicinal chemistry , fluorine , trifluoromethylation , computational chemistry , organic chemistry , molecule , computer science , alkyl , embedded system
Presented is a novel intermolecular radical trifluoromethylfluorosulfonylation of unactivated alkenes under mild reaction conditions with good functional‐group tolerance in the most atom‐economic manner by using readily available Ag(O 2 CCF 2 SO 2 F) and N ‐fluorobenzenesulfonimide (NFSI). Both the trifluoromethyl and sulfonyl groups in the products originate from Ag(O 2 CCF 2 SO 2 F).