Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O 2 CCF 2 SO 2 F) and  N ‐Fluorobenzenesulfonimide | Zendy

Liu Yongan | Zendy; Wu Hao | Zendy; Guo Yong | Zendy; Xiao JiChang | Zendy; Chen QingYun | Zendy; Liu Chao | Zendy

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Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O 2 CCF 2 SO 2 F) and N ‐Fluorobenzenesulfonimide

Author(s) -

Liu Yongan,

Wu Hao,

Guo Yong,

Xiao JiChang,

Chen QingYun,

Liu Chao

Publication year - 2017

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201709663

Subject(s) - trifluoromethyl , chemistry , sulfonyl , intermolecular force , atom (system on chip) , combinatorial chemistry , medicinal chemistry , fluorine , trifluoromethylation , computational chemistry , organic chemistry , molecule , computer science , alkyl , embedded system

Presented is a novel intermolecular radical trifluoromethylfluorosulfonylation of unactivated alkenes under mild reaction conditions with good functional‐group tolerance in the most atom‐economic manner by using readily available Ag(O 2 CCF 2 SO 2 F) and N ‐fluorobenzenesulfonimide (NFSI). Both the trifluoromethyl and sulfonyl groups in the products originate from Ag(O 2 CCF 2 SO 2 F).

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