Spectroscopic Evidence for Ligand Substitution Reactions at the Solid–Liquid Interface of a Sub‐micrometer Gold(I) Carbene Complex | Zendy

Langford Daniel | Zendy; Đurović Mirjana | Zendy; Oszajca Marcin | Zendy; Kuncewicz Joanna | Zendy; van Eldik Rudi | Zendy

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Spectroscopic Evidence for Ligand Substitution Reactions at the Solid–Liquid Interface of a Sub‐micrometer Gold(I) Carbene Complex

Author(s) -

Langford Daniel,

Đurović Mirjana,

Oszajca Marcin,

Kuncewicz Joanna,

van Eldik Rudi

Publication year - 2018

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201708945

Subject(s) - carbene , ligand (biochemistry) , micrometer , colloid , chemistry , solvent , pulmonary surfactant , combinatorial chemistry , shell (structure) , nanotechnology , materials science , organic chemistry , catalysis , biochemistry , physics , receptor , optics , composite material

Colloidal coordination compounds in the sub‐micrometer range were synthesized from a chloro gold(I) carbene complex via the anti‐solvent procedure and stabilized by a surfactant shell of Tween 20. This compound was successfully applied as model system to monitor heterogeneous multiphase ligand substitution reactions at the solid–liquid interface.

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