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Spectroscopic Evidence for Ligand Substitution Reactions at the Solid–Liquid Interface of a Sub‐micrometer Gold(I) Carbene Complex
Author(s) -
Langford Daniel,
Đurović Mirjana,
Oszajca Marcin,
Kuncewicz Joanna,
van Eldik Rudi
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201708945
Subject(s) - carbene , ligand (biochemistry) , micrometer , colloid , chemistry , solvent , pulmonary surfactant , combinatorial chemistry , shell (structure) , nanotechnology , materials science , organic chemistry , catalysis , biochemistry , physics , receptor , optics , composite material
Colloidal coordination compounds in the sub‐micrometer range were synthesized from a chloro gold(I) carbene complex via the anti‐solvent procedure and stabilized by a surfactant shell of Tween 20. This compound was successfully applied as model system to monitor heterogeneous multiphase ligand substitution reactions at the solid–liquid interface.