Sono‐RAFT Polymerization in Aqueous Medium | Zendy

McKenzie Thomas G. | Zendy; Colombo Enrico | Zendy; Fu Qiang | Zendy; Ashokkumar Muthupandian | Zendy; Qiao Greg G. | Zendy

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Sono‐RAFT Polymerization in Aqueous Medium

Author(s) -

McKenzie Thomas G.,

Colombo Enrico,

Fu Qiang,

Ashokkumar Muthupandian,

Qiao Greg G.

Publication year - 2017

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201706771

Subject(s) - chain transfer , raft , reversible addition−fragmentation chain transfer polymerization , polymerization , radical polymerization , chemistry , monomer , aqueous solution , polymer chemistry , polymer , radical , photochemistry , organic chemistry

The ultrasonic irradiation of aqueous solution is demonstrated to be a suitable source of initiating radicals for a controlled radical polymerization when conducted in the presence of a thiocarbonylthio‐containing reversible addition–fragmentation chain transfer (RAFT) agent. This allows for a highly “green” method of externally regulated/controlled polymerization with a potentially broad scope for polymerizable monomers and/or polymer structures.

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