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Highly Bent 1,3‐Digerma‐2‐silaallene
Author(s) -
Sugahara Tomohiro,
Sasamori Takahiro,
Tokitoh Norihiro
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201706297
Subject(s) - moiety , bent molecular geometry , ring (chemistry) , crystallography , chemistry , silicon , stereochemistry , orange (colour) , materials science , organic chemistry , food science
A 1,3‐digerma‐2‐silacyclopenta‐1,2‐diene, that is, a 1,3‐digerma‐2‐silaallene incorporated into a five‐membered ring system, was synthesized and obtained as a stable orange solid. Owing to incorporation into a cyclic framework, the 1,3‐digerma‐2‐silaallene moiety is highly bent, exhibiting a Si 0 character for the central silicon moiety.