Premium
ABi 2 (IO 3 ) 2 F 5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap
Author(s) -
Liu Hongming,
Wu Qi,
Jiang Xingxing,
Lin Zheshuai,
Meng Xianggao,
Chen Xingguo,
Qin Jingui
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201705672
Subject(s) - halide , alkali metal , polar , oxide , band gap , crystallography , chemistry , ionic bonding , crystal structure , group (periodic table) , nonlinear optical , ion , inorganic chemistry , materials science , physics , optoelectronics , nonlinear system , quantum mechanics , organic chemistry , astronomy
A family of nonlinear optical materials that contain the halide, oxide, and oxyhalide polar units simultaneously in a single structure, namely ABi 2 (IO 3 ) 2 F 5 (A=K ( 1 ), Rb ( 2 ), and Cs ( 3 )), have been designed and synthesized. They crystallize in the same polar space group ( P 2 1 ) with a two‐dimensional double‐layered framework constructed by [BiF 5 ] 2− and [BiO 2 F 4 ] 5− units connected to each other by four F atoms, in which two [IO 3 ] − groups are linked to [BiO 2 F 4 ] 5− unit on the same side. A hanging Bi−F bond of [BiF 5 ] 2− unit is located on the other side via ionic interaction with the layer‐inserted alkali metal ions to form three‐dimensional structure. The well‐ordered alignments of these polar units lead to a very strong second‐harmonic generation response of 12 ( 1 ), 9.5 ( 2 ), and 7.5 ( 3 ) times larger than that of potassium dihydrogen phosphate under 1064 nm laser radiation. All of them exhibited a wide energy bandgap over 3.75 eV, suggesting that they will have a high laser damage threshold.