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Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (−)‐Spiroxin C
Author(s) -
Ando Yoshio,
Hanaki Atsuko,
Sasaki Ryota,
Ohmori Ken,
Suzuki Keisuke
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201705562
Subject(s) - enantioselective synthesis , intramolecular force , stereospecificity , chemistry , total synthesis , stereochemistry , organic chemistry , catalysis
Intramolecular photoredox reactions of naphthoquinone derivatives were found to proceed in a stereospecific manner. This method was used as a basis for the enantioselective total synthesis of (−)‐spiroxin C.