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Effect of Selective CF 3 Substitution on the Physical and Chemical Properties of Gold Corroles
Author(s) -
Sudhakar Kolanu,
Mizrahi Amir,
Kosa Monica,
Fridman Natalia,
Tumanskii Boris,
Saphier Magal,
Gross Zeev
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201705007
Subject(s) - chemistry , redox , combinatorial chemistry , catalysis , nanotechnology , corrole , materials science , organic chemistry
Gold corroles are not readily accessible and they display no interesting physical or chemical properties. A facile methodology has now been developed for obtaining selectively CF 3 ‐substituted gold(III) corroles and the introduction of these groups has been found to have an immense effect on the structures of the complexes, their photophysical and redox properties, and on their ability to participate in catalytic processes.