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Ruthenium(II)‐Catalyzed C−C Arylations and Alkylations: Decarbamoylative C−C Functionalizations
Author(s) -
Moselage Marc,
Li Jie,
Kramm Frederik,
Ackermann Lutz
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201701231
Subject(s) - ruthenium , chemistry , catalysis , aryl , combinatorial chemistry , organometallic chemistry , palladium , organic chemistry , alkyl
Ruthenium(II)biscarboxylate catalysis enabled selective C−C functionalizations by means of decarbamoylative C−C arylations. The versatility of the ruthenium(II) catalysis was reflected by widely applicable C−C arylations and C−C alkylations of aryl amides, as well as acids with modifiable pyrazoles, through facile organometallic C−C activation.