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B(C 6 F 5 ) 3 ‐Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes
Author(s) -
Zhang ZiYu,
Liu ZhiYun,
Guo RuiTing,
Zhao YuQuan,
Li Xiang,
Wang XiaoChen
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201700864
Subject(s) - isomerization , catalysis , ring (chemistry) , chemistry , cyclopropane , terminal (telecommunication) , medicinal chemistry , organic chemistry , telecommunications , computer science
Catalytic amounts of B(C 6 F 5 ) 3 promote the ring opening and subsequent isomerization of a series of unactivated cyclopropanes to afford terminal olefins in good yields when a hydrosilane and 2,6‐dibromopyridine are employed as additives.