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Frontispiz: The 2‐Arsaethynolate Anion: Synthesis and Reactivity Towards Heteroallenes
Author(s) -
Hinz Alexander,
Goicoechea Jose M.
Publication year - 2016
Publication title -
angewandte chemie
Language(s) - German
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201683061
Subject(s) - reactivity (psychology) , chemistry , ion , stereochemistry , polymer chemistry , organic chemistry , medicine , alternative medicine , pathology
Anionen . In der Zuschrift auf S. 8678 ff. stellen J. M. Goicoechea und A. Hinz die Synthese des 2‐Arsaethinolat‐Anions, AsCO − , durch Carbonylierung von NaAsH 2 vor. Das Anion reagiert mit ungesättigten Substraten unter Ringschluss zu neuartigen Heterocyclen.

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