Ruthenium(II)‐Catalyzed  meta  C−H Mono‐ and Difluoromethylations by Phosphine/Carboxylate Cooperation | Zendy

Ruan Zhixiong | Zendy; Zhang ShouKun | Zendy; Zhu Cuiju | Zendy; Ruth Paul Niklas | Zendy; Stalke Dietmar | Zendy; Ackermann Lutz | Zendy

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Ruthenium(II)‐Catalyzed meta C−H Mono‐ and Difluoromethylations by Phosphine/Carboxylate Cooperation

Author(s) -

Ruan Zhixiong,

Zhang ShouKun,

Zhu Cuiju,

Ruth Paul Niklas,

Stalke Dietmar,

Ackermann Lutz

Publication year - 2017

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201611595

Subject(s) - phosphine , carboxylate , ruthenium , catalysis , chemistry , cleavage (geology) , substrate (aquarium) , surface modification , scope (computer science) , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , materials science , computer science , oceanography , fracture (geology) , composite material , programming language , geology

Ruthenium(II)‐catalyzed meta ‐selective C−H (di)fluoromethylation was accomplished by phosphine and carboxylate cooperation. The remote C−H functionalization was characterized by ample substrate scope, thereby setting the stage for meta ‐(di)fluoromethylation through facile C−H cleavage.

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