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Not Only Columns: High Hole Mobility in a Discotic Nematic Mesophase Formed by Metal‐Containing Porphyrin‐Core Dendrimers
Author(s) -
Concellón Alberto,
Marcos Mercedes,
Romero Pilar,
Serrano José Luis,
Termine Roberto,
Golemme Attilio
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201611017
Subject(s) - mesophase , discotic liquid crystal , porphyrin , dendrimer , liquid crystal , supramolecular chemistry , materials science , columnar phase , homeotropic alignment , metalation , crystallography , chemistry , photochemistry , polymer chemistry , organic chemistry , crystal structure , optoelectronics
We report a new family of multifunctional liquid‐crystalline porphyrin‐core dendrimers that have coumarin functional groups around the porphyrin core. Porphyrin metalation strongly affects the photophysical properties, and therefore Zn II and Cu II derivatives have also been prepared. All the synthesized dendrimers form a nematic discotic mesophase. Their high tendency for homeotropic alignment makes these dendrimers excellent candidates for device applications, owing to their easy processability, spontaneous alignment between electrodes, and self‐healing of defects because of their dynamic nature. The charge mobility values of these materials are the highest ever reported for a nematic discotic phase. Moreover, these values are similar to the highest values reported for ordered columnar mesophases, and this shows that a supramolecular organization in columns is not necessary to achieve high charge mobility.