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Morphology‐Directed Selective Production of Ethylene or Ethane from CO 2 on a Cu Mesopore Electrode
Author(s) -
Yang Ki Dong,
Ko Woo Ri,
Lee Jun Ho,
Kim Sung Jae,
Lee Hyomin,
Lee Min Hyung,
Nam Ki Tae
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201610432
Subject(s) - mesoporous material , selectivity , catalysis , ethylene , formate , electrode , carbon monoxide , chemical engineering , inorganic chemistry , oxide , copper , materials science , metal , carbon fibers , chemistry , organic chemistry , composite number , engineering , composite material
Abstract The electrocatalytic conversion of CO 2 to value‐added hydrocarbons is receiving significant attention as a promising way to close the broken carbon‐cycle. While most metal catalysts produce C 1 species, such as carbon monoxide and formate, the production of various hydrocarbons and alcohols comprising more than two carbons has been achieved using copper (Cu)‐based catalysts only. Methods for producing specific C 2 reduction outcomes with high selectivity, however, are not available thus far. Herein, the morphological effect of a Cu mesopore electrode on the selective production of C 2 products, ethylene or ethane, is presented. Cu mesopore electrodes with precisely controlled pore widths and depths were prepared by using a thermal deposition process on anodized aluminum oxide. With this simple synthesis method, we demonstrated that C 2 chemical selectivity can be tuned by systematically altering the morphology. Supported by computational simulations, we proved that nanomorphology can change the local pH and, additionally, retention time of key intermediates by confining the chemicals inside the pores.