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Catalytic Enantioselective Arylboration of Alkenylarenes
Author(s) -
Logan Kaitlyn M.,
Brown M. Kevin
Publication year - 2017
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201609844
Subject(s) - enantioselective synthesis , pinacol , chemistry , catalysis , combinatorial chemistry , organic chemistry
A method for the catalytic enantioselective arylboration of alkenylarenes is disclosed. The reaction leads to the formation of 1,1‐diarylalkanes that also incorporate an additional pinacol boronic ester which can be easily transformed to a variety of groups. The products are formed with excellent diastereoselectivities and enantioselectivities.