A Germylene Stabilized by Homoconjugation | Zendy

Dong Zhaowen | Zendy; Reinhold Crispin R. W. | Zendy; Schmidtmann Marc | Zendy; Müller Thomas | Zendy

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A Germylene Stabilized by Homoconjugation

Author(s) -

Dong Zhaowen,

Reinhold Crispin R. W.,

Schmidtmann Marc,

Müller Thomas

Publication year - 2016

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201609576

Subject(s) - chemistry , bimetallic strip , reactivity (psychology) , germanium , hafnium , nucleophile , linker , double bond , atom (system on chip) , bicyclic molecule , tungsten , germanium compounds , photochemistry , medicinal chemistry , inorganic chemistry , polymer chemistry , metal , catalysis , organic chemistry , silicon , zirconium , medicine , alternative medicine , pathology , computer science , embedded system , operating system

The synthesis of a bicyclic germylene from the reaction of a germole dianion with hafnocene dichloride is reported. This germylene is stabilized by a homoconjugative interaction of the dicoordinated germanium atom with a remote C=C double bond. First reactivity studies revealed its nucleophilic character and resulted in the synthesis of bimetallic hafnium/iron and hafnium/tungsten complexes with a germylene group linker.

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