Switchable Surface Hydrophobicity–Hydrophilicity of a Metal–Organic Framework | Zendy

RodríguezHermida Sabina | Zendy; Tsang Min Ying | Zendy; Vignatti Claudia | Zendy; Stylianou Kyriakos C. | Zendy; Guillerm Vincent | Zendy; PérezCarvajal Javier | Zendy; Teixidor Francesc | Zendy; Viñas Clara | Zendy; ChoquesilloLazarte Duane | Zendy; VerdugoEscamilla Cristóbal | Zendy; Peral Inmaculada | Zendy; Juanhuix Jordi | Zendy; Verdaguer Albert | Zendy; Imaz Inhar | Zendy; Maspoch Daniel | Zendy; Giner Planas José | Zendy

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Switchable Surface Hydrophobicity–Hydrophilicity of a Metal–Organic Framework

Author(s) -

RodríguezHermida Sabina,

Tsang Min Ying,

Vignatti Claudia,

Stylianou Kyriakos C.,

Guillerm Vincent,

PérezCarvajal Javier,

Teixidor Francesc,

Viñas Clara,

ChoquesilloLazarte Duane,

VerdugoEscamilla Cristóbal,

Peral Inmaculada,

Juanhuix Jordi,

Verdaguer Albert,

Imaz Inhar,

Maspoch Daniel,

Giner Planas José

Publication year - 2016

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201609295

Subject(s) - superhydrophilicity , linker , wetting , carborane , metal organic framework , contact angle , nanotechnology , materials science , metal , chemistry , chemical engineering , organic chemistry , adsorption , computer science , engineering , composite material , operating system

Materials with surfaces that can be switched from high/superhydrophobicity to superhydrophilicity are useful for myriad applications. Herein, we report a metal–organic framework (MOF) assembled from Zn II ions, 1,4‐benzenedicarboxylate, and a hydrophobic carborane‐based linker. The MOF crystal‐surface can be switched between hydrophobic and superhydrophilic through a chemical treatment to remove some of the building blocks.

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