Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis | Zendy

Gawin Rafał | Zendy; Kozakiewicz Anna | Zendy; Guńka Piotr A. | Zendy; Dąbrowski Paweł | Zendy; Skowerski Krzysztof | Zendy

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Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis

Author(s) -

Gawin Rafał,

Kozakiewicz Anna,

Guńka Piotr A.,

Dąbrowski Paweł,

Skowerski Krzysztof

Publication year - 2017

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201609009

Subject(s) - carbene , ruthenium , alkyl , olefin metathesis , metathesis , chemistry , olefin fiber , acyclic diene metathesis , transition metal carbene complex , combinatorial chemistry , organic synthesis , salt metathesis reaction , organic chemistry , catalysis , polymerization , polymer

The state‐of‐the‐art in olefin metathesis is application of N‐heterocyclic carbene (NHC)‐containing ruthenium alkylidenes for the formation of internal C=C bonds and of cyclic alkyl amino carbene (CAAC)‐containing ruthenium benzylidenes in the production of terminal olefins. A straightforward synthesis of bis(CAAC)Ru indenylidene complexes, which are highly effective in the formation of both terminal and internal C=C bonds at loadings as low as 1 ppm, is now reported.

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