Water‐in‐Supercritical CO 2  Microemulsion Stabilized by a Metal Complex | Zendy

Luo Tian | Zendy; Zhang Jianling | Zendy; Tan Xiuniang | Zendy; Liu Chengcheng | Zendy; Wu Tianbin | Zendy; Li Wei | Zendy; Sang Xinxin | Zendy; Han Buxing | Zendy; Li Zhihong | Zendy; Mo Guang | Zendy; Xing Xueqing | Zendy; Wu Zhonghua | Zendy

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Water‐in‐Supercritical CO 2 Microemulsion Stabilized by a Metal Complex

Author(s) -

Luo Tian,

Zhang Jianling,

Tan Xiuniang,

Liu Chengcheng,

Wu Tianbin,

Li Wei,

Sang Xinxin,

Han Buxing,

Li Zhihong,

Mo Guang,

Xing Xueqing,

Wu Zhonghua

Publication year - 2016

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201608695

Subject(s) - microemulsion , supercritical fluid , metal , solubility , chemistry , chemical engineering , supercritical carbon dioxide , inorganic chemistry , organic chemistry , pulmonary surfactant , biochemistry , engineering

Herein we propose for the first time the utilization of a metal complex for forming water‐in‐supercritical CO 2 (scCO 2 ) microemulsions. The water solubility in the metal‐complex‐stabilized microemulsion is significantly improved compared with the conventional water‐in‐scCO 2 microemulsions stabilized by hydrocarbons. Such a microemulsion provides a promising route for the in situ CO 2 reduction catalyzed by a metal complex at the water/scCO 2 interface.

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