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Hydrothermal Synthesis of Metal–Polyphenol Coordination Crystals and Their Derived Metal/N‐doped Carbon Composites for Oxygen Electrocatalysis
Author(s) -
Wei Jing,
Liang Yan,
Hu Yaoxin,
Kong Biao,
Zhang Jin,
Gu Qinfen,
Tong Yuping,
Wang Xianbiao,
Jiang San Ping,
Wang Huanting
Publication year - 2016
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201606327
Subject(s) - catalysis , electrocatalyst , metal , hydrothermal synthesis , cobalt , metal organic framework , materials science , polymerization , inorganic chemistry , chemical engineering , oxygen evolution , carbon fibers , metal ions in aqueous solution , hydrothermal circulation , chemistry , polyphenol , polymer , organic chemistry , composite number , composite material , electrochemistry , electrode , adsorption , antioxidant , engineering
Cobalt (or iron)–polyphenol coordination polymers with crystalline frameworks are synthesized for the first time. The crystalline framework is formed by the assembly of metal ions and polyphenol followed by oxidative self‐polymerization of the organic ligands (polyphenol) during hydrothermal treatment in alkaline condition. As a result, such coordination crystals are even partly stable in strong acid (such as 2 m HCl). The metal (Co or Fe)‐natural abundant polyphenol (tannin) coordination crystals are a renewable source for the fabrication of metal/carbon composites as a nonprecious‐metal catalyst, which show high catalytic performance for both oxygen reduction reaction and oxygen evolution reaction. Such excellent performance makes metal–polyphenol coordination crystals an efficient precursor to fabricate low‐cost catalysts for the large‐scale application of fuel cells and metal–air batteries.