The Oxygen‐Rich Beryllium Oxides BeO 4  and BeO 6 | Zendy

Zhang Qingnan | Zendy; Jerabek Paul | Zendy; Chen Mohua | Zendy; Zhou Mingfei | Zendy; Frenking Gernot | Zendy

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The Oxygen‐Rich Beryllium Oxides BeO 4 and BeO 6

Author(s) -

Zhang Qingnan,

Jerabek Paul,

Chen Mohua,

Zhou Mingfei,

Frenking Gernot

Publication year - 2016

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201606154

Subject(s) - ozonide , chemistry , beryllium , oxygen , infrared spectroscopy , spectroscopy , photochemistry , absorption spectroscopy , infrared , electronic structure , computational chemistry , physics , organic chemistry , quantum mechanics , ozone , optics

Two novel isomers of BeO 4 with the structures OBeOOO and OBe(O 3 ) in the electronic triplet state have been prepared as well as the known disuperoxide complex Be(O 2 ) 2 in solid noble‐gas matrices. We also report the synthesis of the oxygen‐rich bis(ozonide) complex Be(O 3 ) 2 in the triplet state which has a D 2 d equilibrium geometry. The molecular structures were identified by infrared absorption spectroscopy with isotopic substitutions as well as quantum chemical calculations.

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