Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands | Zendy

Kuriyama Shogo | Zendy; Arashiba Kazuya | Zendy; Tanaka Hiromasa | Zendy; Matsuo Yuki | Zendy; Nakajima Kazunari | Zendy; Yoshizawa Kazunari | Zendy; Nishibayashi Yoshiaki | Zendy

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Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands

Author(s) -

Kuriyama Shogo,

Arashiba Kazuya,

Tanaka Hiromasa,

Matsuo Yuki,

Nakajima Kazunari,

Yoshizawa Kazunari,

Nishibayashi Yoshiaki

Publication year - 2016

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201606090

Subject(s) - chemistry , catalysis , cobalt , hydrazine (antidepressant) , pincer movement , ammonia , ligand (biochemistry) , pincer ligand , nitrogen , inorganic chemistry , polymer chemistry , medicinal chemistry , organic chemistry , receptor , chromatography , biochemistry

The direct formation of ammonia from molecular dinitrogen under mild reaction conditions was achieved by using new cobalt dinitrogen complexes bearing an anionic PNP‐type pincer ligand. Up to 15.9 equivalents of ammonia were produced based on the amount of catalyst together with 1.0 equivalent of hydrazine (17.9 equiv of fixed nitrogen atoms).

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