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Silver Complexes of Dihalogen Molecules
Author(s) -
Malinowski Przemysław J.,
Himmel Daniel,
Krossing Ingo
Publication year - 2016
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201603741
Subject(s) - raman spectroscopy , crystallography , molecule , chemistry , crystal structure , materials science , organic chemistry , physics , optics
The perfluorohexane‐soluble and donor‐free silver compound Ag( A ) ( A =Al(OR F ) 4 ; R F =C(CF 3 ) 3 ) prepared using a facile novel route has unprecedented capabilities to form unusual and weakly bound complexes. Here, we report on the three dihalogen–silver complexes Ag(Cl 2 ) A , Ag(Br 2 ) A , and Ag(I 2 ) A derived from the soluble silver compound Ag( A ) (characterized by single‐crystal/powder XRD, Raman spectra, and quantum‐mechanical calculations).
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