Isolation and Characterization, Including by X‐ray Crystallography, of Contact and Solvent‐Separated Ion Pairs of Silenyl Lithium Species

Reaction of bromoacylsilane 1 (pink solution) with t Bu 2 MeSiLi (3.5 equiv) in a 4:1 hexane:THF solvent mixture at −78 °C to room temperature yields the solvent separated ion pair (SSIP) of silenyl lithium E ‐[( t BuMe 2 Si)( t Bu 2 MeSi)C=Si(SiMe t Bu 2 )] − [Li⋅4THF] + 2 a (green–blue solution). Removal of the solvent and addition of benzene converts 2 a into the corresponding contact ion pair (CIP) 2 b (violet–red solution) with two THF molecules bonded to the lithium atom. The 2 a ⇌ 2 b interconversion is reversible upon THF⇌ benzene solvent change. Both 2 a and 2 b were characterized by X‐ray crystallography, NMR and UV/Vis spectroscopy, and theoretical calculations. The degree of dissociation of the Si−Li bond has a large effect on the visible spectrum (and thus color) and on the silenylic 29 Si NMR chemical shift, but a small effect on the molecular structure. This is the first report of the X‐ray molecular structure of both the SSIP and the CIP of any R 2 E=E′RM species (E=C, Si; E′=C, Si; M=metal).