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A Modular Synthetic Approach to Monocyclic 1,4‐Azaborines
Author(s) -
Liu Xuguang,
Zhang Yuanzhe,
Li Bo,
Zakharov Lev N.,
Vasiliu Monica,
Dixon David A.,
Liu ShihYuan
Publication year - 2016
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201602840
Subject(s) - heteroatom , isomerization , olefin fiber , modular design , chemistry , combinatorial chemistry , computational chemistry , organic chemistry , computer science , ring (chemistry) , catalysis , operating system
A simple and general method for the synthesis of a wide range of monocyclic 1,4‐azaborines, including the first examples containing B heteroatoms is described. Post‐heterocycle‐formation olefin isomerization was employed as a key strategy. This new synthetic method provides fundamental insight into the resonance stabilization and photophysical properties of 1,4‐azaborines.