Photoassisted Synthesis of Complex Molecular Architectures: Dearomatization of Benzenoid Arenes with Aza‐ o ‐xylylenes via an Unprecedented [2+4] Reaction Topology | Zendy

Kuznetsov Dmitry M. | Zendy; Mukhina Olga A. | Zendy; Kutateladze Andrei G. | Zendy

Premium

Photoassisted Synthesis of Complex Molecular Architectures: Dearomatization of Benzenoid Arenes with Aza‐ o ‐xylylenes via an Unprecedented [2+4] Reaction Topology

Author(s) -

Kuznetsov Dmitry M.,

Mukhina Olga A.,

Kutateladze Andrei G.

Publication year - 2016

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201602288

Subject(s) - intramolecular force , cycloaddition , synthon , chemistry , topology (electrical circuits) , excited state , combinatorial chemistry , photochemistry , computational chemistry , stereochemistry , organic chemistry , catalysis , physics , mathematics , atomic physics , combinatorics

A new method was developed for the photoinduced dearomatization of arenes through an intramolecular cycloaddition with aza‐ o ‐xylylenes generated by excited‐state intramolecular proton transfer (ESIPT) in the readily available photoprecursors. The [2+4] topology of this cycloaddition is unprecedented for photo‐dearomatizations of benzenoid aromatic carbocycles. It provides rapid access to novel heterocycles, cyclohexadieno‐oxazolidino‐quinolinols, as valuable synthons for a broad range of post‐photochemical transformations.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research