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[2](1,3)Adamantano[2](2,7)pyrenophane: A Hydrocarbon with a Large Dipole Moment
Author(s) -
Kahl Paul,
Wagner J. Philipp,
Balestrieri Ciro,
Becker Jonathan,
Hausmann Heike,
Bodwell Graham J.,
Schreiner Peter R.
Publication year - 2016
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201602201
Subject(s) - diamondoid , adamantane , pyrene , dipole , hydrocarbon , moiety , chemistry , moment (physics) , computational chemistry , polycyclic aromatic hydrocarbon , chemical physics , photochemistry , stereochemistry , crystallography , organic chemistry , molecule , physics , classical mechanics
The fusion of the sp 3 ‐hybridized parent diamondoid adamantane with the sp 2 ‐hybridized pyrene results in a hybrid structure with a very large dipole moment which arises from bending the pyrene moiety. Presented herein is the synthesis, study of the electronic and optical properties, as well as the dynamic behavior of this new hydrocarbon.