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Mild C−H/C−C Activation by Z ‐Selective Cobalt Catalysis
Author(s) -
Zell Daniel,
Bu Qingqing,
Feldt Milica,
Ackermann Lutz
Publication year - 2016
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201601778
Subject(s) - cobalt , catalysis , cationic polymerization , selectivity , chemistry , cleavage (geology) , combinatorial chemistry , materials science , polymer chemistry , inorganic chemistry , organic chemistry , fracture (geology) , composite material
Cationic cobalt complexes enable unprecedented cobalt‐catalyzed C−H/C−C functionalizations with unique selectivity features. The versatile cobalt catalyst proved broadly applicable, enabled efficient C−H/C−C cleavage at room temperature, and delivered Z‐alkenes with excellent diastereocontrol.