Synthesis of 1,1‐Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron | Zendy

Morinaga Akira | Zendy; Nagao Kazunori | Zendy; Ohmiya Hirohisa | Zendy; Sawamura Masaya | Zendy

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Synthesis of 1,1‐Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

Author(s) -

Morinaga Akira,

Nagao Kazunori,

Ohmiya Hirohisa,

Sawamura Masaya

Publication year - 2015

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201509218

Subject(s) - catalysis , chemistry , terminal (telecommunication) , base (topology) , reaction conditions , brønsted–lowry acid–base theory , combinatorial chemistry , medicinal chemistry , organic chemistry , computer science , mathematics , mathematical analysis , telecommunications

A method for the synthesis of 1,1‐diborylalkenes through a Brønsted base catalyzed reaction between terminal alkynes and bis(pinacolato)diboron has been developed. The procedure allows direct synthesis of functionalized 1,1‐diborylalkenes from various terminal alkynes including propiolates, propiolamides, and 2‐ethynylazoles.

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