Premium
A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs
Author(s) -
Mouchaham Georges,
Cooper Lucy,
Guillou Nathalie,
Martineau Charlotte,
Elkaïm Erik,
Bourrelly Sandrine,
Llewellyn Philip L.,
Allain Clémence,
Clavier Gilles,
Serre Christian,
Devic Thomas
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201507058
Subject(s) - zirconium , carboxylate , ligand (biochemistry) , chemical stability , chemistry , stability (learning theory) , materials science , chemical engineering , inorganic chemistry , stereochemistry , organic chemistry , computer science , biochemistry , receptor , engineering , machine learning
A novel Zr‐chain based MOF, namely MIL‐163, was designed and successfully synthesized using a bis‐1,2,3‐trioxobenzene ligand. Endowed with large square‐shaped channels of 12 Å width, it shows remarkable water uptake (ca. 0.6 cm 3 g −1 at saturating vapor pressure) and a remarkable stability in simulated physiological media, where archetypical Zr carboxylate MOFs readily degrade.