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Synthesis and Reactivity of a Neutral, Three‐Coordinate Platinum(II) Complex Featuring Terminal Amido Ligation
Author(s) -
Kelly Colin M.,
Kwon DooHyun,
Ferguson Michael J.,
Bischof Steven M.,
Sydora Orson L.,
Ess Daniel H.,
Stradiotto Mark,
Turculet Laura
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201506871
Subject(s) - chemistry , reactivity (psychology) , platinum , amide , terminal (telecommunication) , stoichiometry , stereochemistry , ligation , crystallography , catalysis , organic chemistry , medicine , telecommunications , alternative medicine , microbiology and biotechnology , pathology , computer science , biology
Abstract A crystallographically characterized three‐coordinate, formally 14 electron Pt II complex 1 featuring terminal amido ligation is reported. Computational analysis revealed relatively weak π donation from the amide lone pair to platinum and supports a 14‐electron assignment for 1 . Stoichiometric reactivity studies confirmed the viability of net OH and CH addition across, as well as isonitrile insertion into, the terminal platinum–amido linkage of 1 .