Synthesis and Reactivity of a Neutral, Three‐Coordinate Platinum(II) Complex Featuring Terminal Amido Ligation | Zendy

Kelly Colin M. | Zendy; Kwon DooHyun | Zendy; Ferguson Michael J. | Zendy; Bischof Steven M. | Zendy; Sydora Orson L. | Zendy; Ess Daniel H. | Zendy; Stradiotto Mark | Zendy; Turculet Laura | Zendy

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Synthesis and Reactivity of a Neutral, Three‐Coordinate Platinum(II) Complex Featuring Terminal Amido Ligation

Author(s) -

Kelly Colin M.,

Kwon DooHyun,

Ferguson Michael J.,

Bischof Steven M.,

Sydora Orson L.,

Ess Daniel H.,

Stradiotto Mark,

Turculet Laura

Publication year - 2015

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201506871

Subject(s) - chemistry , reactivity (psychology) , platinum , amide , terminal (telecommunication) , stoichiometry , stereochemistry , ligation , crystallography , catalysis , organic chemistry , medicine , telecommunications , alternative medicine , microbiology and biotechnology , pathology , computer science , biology

A crystallographically characterized three‐coordinate, formally 14 electron Pt II complex 1 featuring terminal amido ligation is reported. Computational analysis revealed relatively weak π donation from the amide lone pair to platinum and supports a 14‐electron assignment for 1 . Stoichiometric reactivity studies confirmed the viability of net OH and CH addition across, as well as isonitrile insertion into, the terminal platinum–amido linkage of 1 .

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