Premium
Rhodium‐Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane
Author(s) -
Morimoto Masao,
Miura Tomoya,
Murakami Masahiro
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201506328
Subject(s) - borylation , rhodium , chemistry , norbornene , cationic polymerization , catalysis , alkene , adduct , organic chemistry , medicinal chemistry , polymerization , alkyl , polymer , aryl
Aliphatic terminal alkenes react with pinacolborane at ambient temperature to afford dehydrogenative borylation compounds as the major product when i Pr‐Foxap is used as the ligand with cationic rhodium(I) in the presence of norbornene, which acts as the sacrificial hydrogen acceptor. The reaction is applied to the one‐pot syntheses of aldehydes and homoallylic alcohols from aliphatic terminal alkenes.