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Conversion of Carbon Dioxide by Methane Reforming under Visible‐Light Irradiation: Surface‐Plasmon‐Mediated Nonpolar Molecule Activation
Author(s) -
Liu Huimin,
Meng Xianguang,
Dao Thang Duy,
Zhang Huabin,
Li Peng,
Chang Kun,
Wang Tao,
Li Mu,
Nagao Tadaaki,
Ye Jinhua
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201504933
Subject(s) - photochemistry , syngas , methane , catalysis , irradiation , molecule , chemistry , surface plasmon resonance , plasmon , surface plasmon , excited state , materials science , chemical engineering , nanotechnology , optoelectronics , nanoparticle , organic chemistry , atomic physics , physics , nuclear physics , engineering
A novel CO 2 photoreduction method, CO 2 conversion through methane reforming into syngas (DRM) was adopted as an efficient approach to not only reduce the environmental concentration of the greenhouse gas CO 2 but also realize the net energy storage from solar energy to chemical energy. For the first time it is reported that gold, which was generally regarded to be inactive in improving the performance of a catalyst in DRM under thermal conditions, enhanced the catalytic performance of Rh/SBA‐15 in DRM under visible‐light irradiation (1.7 times, CO 2 conversion increased from 2100 to 3600 μmol g −1 s −1 ). UV/Vis spectra and electromagnetic field simulation results revealed that the highly energetic electrons excited by local surface plasmon resonances of Au facilitated the polarization and activation of CO 2 and CH 4 with thermal assistance. This work provides a new route for CO 2 photoreduction and offers a distinctive method to photocatalytically activate nonpolar molecules.