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Metal–Organic Frameworks (MOFs) of a Cubic Metal Cluster with Multicentered Mn I Mn I Bonds
Author(s) -
Hu HuanCheng,
Hu HanShi,
Zhao Bin,
Cui Ping,
Cheng Peng,
Li Jun
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201504758
Subject(s) - delocalized electron , crystallography , manganese , density functional theory , oxidation state , cluster (spacecraft) , chemistry , metal , atomic orbital , chemical bond , antiferromagnetism , crystal structure , electron , materials science , computational chemistry , condensed matter physics , physics , organic chemistry , quantum mechanics , computer science , programming language
MOFs with both multicentered metal–metal bonds and low‐oxidation‐state (LOS) metal ions have been underexplored hitherto. Here we report the first cubic [Mn I 8 ] cluster‐based MOF ( 1 ) with multicentered Mn I Mn I bonds and +1 oxidation state of manganese (Mn I or Mn(I)), as is supported by single‐crystal structure determination, XPS analyses, and quantum chemical studies. Compound 1 possesses the shortest Mn I Mn I bond of 2.372 Å. Theoretical studies with density functional theory (DFT) reveal extensive electron delocalization over the [Mn I 8 ] cube. The 48 electrons in the [Mn I 8 ] cube fully occupy half of the 3d‐based and the lowest 4s‐based bonding orbitals, with six electrons lying at the nonbonding 3d‐orbitals. This bonding feature renders so‐called cubic aromaticity. Magnetic properties measurements show that 1 is an antiferromagnet. This work is expected to inspire further investigation of cubic metal–metal bonding, MOF materials with LOS metals, and metalloaromatic theory.