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Formation and Characterization of the Boron Dicarbonyl Complex [B(CO) 2 ] −
Author(s) -
Zhang Qingnan,
Li WanLu,
Xu CongQiao,
Chen Mohua,
Zhou Mingfei,
Li Jun,
Andrada Diego M.,
Frenking Gernot
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201503686
Subject(s) - boron , characterization (materials science) , chemistry , aluminium , crystallography , materials science , nanotechnology , organic chemistry
We report the synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO) 2 ] − . The bonding situation is analyzed and compared with the aluminum homologue [Al(CO) 2 ] − using state‐of‐the‐art quantum chemical methods.