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Barium‐Mediated Cross‐Dehydrocoupling of Hydrosilanes with Amines: A Theoretical and Experimental Approach
Author(s) -
Bellini Clément,
Carpentier JeanFrançois,
Tobisch Sven,
Sarazin Yann
Publication year - 2015
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201502956
Subject(s) - chemistry , chemoselectivity , amide , nucleophile , barium , metal , silane , medicinal chemistry , hydrogen , limiting , catalysis , inorganic chemistry , organic chemistry , mechanical engineering , engineering
Alkaline‐earth (most prominently barium) complexes of the type [Ae{N(SiMe 3 ) 2 } 2 ⋅(THF) x ] and [{N^N}Ae{N(SiMe 3 ) 2 }⋅(THF) x ] are very active and productive precatalysts (TON=396, TOF up to 3600 h −1 ; Ca